[μ-N,N,N′,N′-Tetrakis(2-pyridylmethyl)hexane-1,6-diamine]bis[dichloridomanganese(II)]
نویسندگان
چکیده
The asymmetric unit of the title compound, [Mn(2)Cl(4)(C(30)H(36)N(6))], contains one-half of the formula unit; a centre of inversion is located at the mid-point of the mol-ecule. The two Mn(2+) ions are bridged by the dual tri-dentate N,N,N',N'-tetra-kis(2-pyridylmeth-yl)hexane-1,6-diamine ligand to form a dinuclear complex. Each Mn atom is five-coordinated in an approximately square-pyramidal geometry by three N atoms from the ligand and two Cl atoms. Inter-molecular π-π inter-actions between adjacent pyridine rings with a centroid-centroid distance of 3.576 (2) Å are reported.
منابع مشابه
catena-Poly[[[aquamanganese(II)]-di-μ-sulfato-[aquamanganese(II)]-μ-N,N,N′,N′-tetrakis(2-pyridylmethyl)hexane-1,6-diamine] hexahydrate]
In the polymeric title compound, {[Mn(2)(SO(4))(2)(C(30)H(36)N(6))(H(2)O)(2)]·6H(2)O}(n), the two Mn(2+) ions are bridged by two sulfate anions to form dinuclear complexes, and these dinuclear species are linked by the hexa-dentate ligand N,N,N',N'-tetra-kis(2-pyridylmeth-yl)hexane-1,6-diamine (tphn), forming a one-dimensional chain structure running in the [101] direction. The repeat unit of t...
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